There were some big upsets at the 2007 European Championship. Here are some of the biggest ones:

GM Georgiev Kiril 0 – 1 IM Holzke Frank
IM Urban Klaudiusz 1 – 0 GM Naiditsch Arkadij
GM Gashimov Vugar 0 – 1 GM Handke Florian
IM Esen Baris 1 – 0 GM Socko Bartosz
IM Orlov Andrey 1 – 0 GM Asrian Karen
IM Szabo Krisztian 1 – 0 GM Azmaiparashvili Zurab

Here is the official website.

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Chess Daily News from Susan Polgar
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